cis-Dichlorobis(diethylsulfide)platinum(II)
- CasNo:15442-57-6
Product Description
Buy high quality and low price cis-Dichlorobis(diethylsulfide)platinum(II) 15442-57-6 now
- Molecular Formula: C8H20Cl2PtS2
- Molecular Weight: 446.365
- Appearance/Colour: Yellow-green powder
- Melting Point: 105 °C(lit.)
- Boiling Point: 94.4 °C at 760 mmHg
- PSA： 50.60000
- LogP: 4.89530
cis-Dichlorobis(diethylsulfide)platinum(II)(Cas 15442-57-6) Usage
InChI:InChI=1/2C4H10S.2ClH.Pt/c2*1-3-5-4-2;;;/h2*3-4H2,1-2H3;2*1H;/q;;;;+2/p-2
15442-57-6 Relevant articles
9,10-dihydroplatinaanthracenes with aromatic diimine ligands: Syntheses and spectroscopic and computational studies of new luminescent materials
De Crisci, Antonio G.,Lough, Alan J.,Multani, Kanwarpal,Fekl, Ulrich
, p. 1765 - 1779 (2009/02/01)
9,10-Dihydroplatinaanthracenes with arom...
Cis-Dichloridobis(diethyl sulfide-κS)platinum(II) at 295 and 150 K
Hansson, Christian
, p. m361-m363 (2008/09/16)
The title compound, cis-[PtCl2(C4H10S)2]...
Nucleophilic Discrimination and the trans Effect. The Kinetics of Displacement of X from trans-n- (L=Me2SO, Et2S, PMe3, PEt3, PPh3, or AsEt3; X=Cl, n=1; X=MeOH, n=0) by Neutral and Anionic Nucleophiles
Tobe, Martin L.,Treadgold, Andrew T.
, p. 2347 - 2352 (2007/10/02)
The kinetics of the reaction trans-n- + ...
Fast Cis-Trans Isomerization of Square-Planar Bis(diethyl sulfide)platinum(II) Complexes. Reaction of cis-Dichlorobis(diethyl sulfide)platinum(II) with Mesityllithium
Tobita, Hiromi,Habazaki, Hiroki,Ogino, Hiroshi
, p. 797 - 799 (2007/10/02)
Reaction of cis- with a slight excess of...
15442-57-6 Process route
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-
10025-99-7
potassium tetrachloroplatinate(II)
-
-
352-93-2
diethyl sulphide
-
-
14873-92-8,20244-83-1,15337-84-5,15442-57-6
cis-dichlorobis(diethylsulfide)platinum(II)
-
-
14873-92-8,20244-83-1,15442-57-6,15337-84-5
trans-dichlorobis(diethyl sulfide)platinum(II)
| Conditions | Yield |
|---|---|
|
In
water;
byproducts: KCl; (inert atm.); addn. of diethylsulfide to aq. soln. of platinum compd., stirring for 24 h; evapn. at 25°C in vac., extn. (hot benzene), filtration, concg., cooling to 0°C, filtration, washing with hexane, NMR;
|
83%
|
|
In
not given;
formation on shaking of K2(PtCl4)-soln. with S(C2H5)2;; contains approx. 20% cis-compound; seperation with concd. acetaldehyde or a mixture of aldehyde and alcohol;;
|
-
-
10025-99-7
potassium tetrachloroplatinate(II)
-
-
352-93-2
diethyl sulphide
-
-
14873-92-8,20244-83-1,15337-84-5,15442-57-6
cis-dichlorobis(diethylsulfide)platinum(II)
-
-
14873-92-8,20244-83-1,15442-57-6,15337-84-5
trans-dichlorobis(diethyl sulfide)platinum(II)
| Conditions | Yield |
|---|---|
|
In
water;
byproducts: KCl; (inert atm.); addn. of diethylsulfide to aq. soln. of platinum compd., stirring for 24 h; evapn. at 25°C in vac., extn. (hot benzene), filtration, concg., cooling to 0°C, filtration, washing with hexane, NMR;
|
83%
|
|
In
not given;
formation on shaking of K2(PtCl4)-soln. with S(C2H5)2;; contains approx. 20% cis-compound; seperation with concd. acetaldehyde or a mixture of aldehyde and alcohol;;
|
15442-57-6 Upstream products
-
14873-92-8
trans-dichlorobis(diethyl sulfide)platinum(II)
-
352-93-2
diethyl sulphide
-
10025-99-7
potassium tetrachloroplatinate(II)
-
7647-01-0
hydrogenchloride
15442-57-6 Downstream products
-
22518-41-8
{Pt
Br2} -
14873-92-8
trans-dichlorobis(diethyl sulfide)platinum(II)
-
12080-89-6
{Ptaes2 Cl4 }
-
121122-22-3
dichloro(N,N-dimethyl-3-diphenylphosphinopropylamine)platinum(II)